She's a natural beauty both on camera and off, and earlier today (September 2) Blake Lively was spotted looking hot on the set of "Gossip Girl."

The "Sisterhood of the Traveling Pants" babe arrived on location at The Gates club in Midtown Manhattan sporting a purple cleavage-baring blouse with a grey cardigan, khaki skirt, and beige heels.

Along with her CW commitments in New York City, Miss Lively has also been flying up to Boston, Massachusetts to film her new movie "The Town."

Blake stars alongside Ben Affleck and Chris Cooper in the thriller about a career criminal who tries to turn his life around, and is faced with the mistakes of his past as he falls in love with a bank manager.

Enjoy the pictures of Blake Lively on the set of "Gossip Girl" (September 2).